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Iron in the fertigation of fruit trees

Iron in the fertigation of fruit trees
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Iron (Fe) in the fertigation of fruit trees

Chelate forms, stability against pH, method of application & rates
Pastopoulos Agronomics — technical note for growers
1

Why chelated iron is needed

In calcareous soils with a high pH — the norm across northern Greece — iron is converted into insoluble forms (Fe(OH)₃) and is not available to the root, producing iron chlorosis: yellowing between the veins of the young leaves. Supplying chelated Fe through the drip system keeps the iron soluble so that the roots can take it up.

2

Chelate stability against soil pH

Every chelating agent holds iron in solution only up to a certain pH — above it the Fe precipitates and the product stops working.

acid
neutral
alkaline (calcareous soils)
pH 456789
Fe-EDTA
stable to ~6.5
Fe-DTPA
stable to ~7.0–7.5
Fe-EDDHA / Fe-HBED
stable to pH 9
3

The four main chelated iron forms

Fe-EDDHA

ethylenediamine-di(o-hydroxyphenylacetic acid)
Stable at pH 4–9
  • The most suitable form for calcareous and alkaline soils
  • Critical: ask for a high percentage of the ortho-ortho isomer — that is the active fraction
  • Ideal for drip irrigation — it does not precipitate in the emitters
  • Long-lasting effect, fewer repeat applications

Fe-HBED

N,N'-bis(2-hydroxybenzyl)ethylenediamine
Stable to pH 9
  • Stability comparable to EDDHA on alkaline soils
  • Less widely available commercially in Greece — check supply first
  • A good alternative to EDDHA where it can be obtained

Fe-DTPA

diethylenetriaminepentaacetic acid
Stable to about pH 7.0–7.5
  • Intermediate stability — suitable for slightly alkaline soils
  • Above pH 7.5 it begins to break down
  • A good choice where the irrigation water has a moderately high pH

Fe-EDTA

ethylenediaminetetraacetic acid
Stable to about pH 6.5
  • Suitable only for acid or neutral soils
  • On alkaline soils it precipitates very quickly — poor performance
  • Can be combined with local acidification of the irrigation water
Practical note: on most calcareous Greek soils (pH 7.5–8.5), only Fe-EDDHA (or Fe-HBED where available) keeps the iron genuinely soluble and usable through a drip system. Under those conditions Fe-EDTA and Fe-DTPA lose their effect rapidly.
4

How it is applied through fertigation

Injection through the drip system: the chelated Fe is dissolved in a stock tank and injected with a dosing pump or a Venturi into the main line, so that it is distributed evenly through the root zone of every tree.

Order of operations: irrigate first with clean water for 10–15 minutes → inject the Fe solution in the middle of the irrigation cycle → carry on with clean water for a further 15–20 minutes, so that the iron is carried down into the root zone and the lines are flushed clear.
5

Timing through the growing season

🌱

Before bloom

First application shortly before bud swell

🌸

Fruit set

Second application as fruit and shoot growth begins

🍃

Rapid growth

Third application if chlorosis appears on new leaves

🍑

Fruit development

Optional top-up on strongly calcareous blocks

6

Indicative Fe-EDDHA rates (6% Fe, ortho-ortho) for fruit trees

Tree age / sizeElemental Fe per tree per yearNumber of applicationsComment
Young trees (1–3 years)1–2 g Fe
(≈17–33 g of a 6% Fe-EDDHA product)
1–2Small rhizosphere, lower rate
Trees in full development (4–10 years)2–4 g FeMost common rate
(≈33–67 g of a 6% Fe-EDDHA product)
2–3Splitting into 2–3 applications improves effectiveness
Mature / large trees (over 10 years)4–6 g Fe
(≈67–100 g of a 6% Fe-EDDHA product)
2–3Under severe chlorosis, adjust to the leaf symptoms
Expressed per unit area (guideline)≈1–5 kg Fe/ha/year
(≈20–80 kg of a 6% Fe-EDDHA product per ha)
Follows from the per-tree rate multiplied by planting density
Correction to an earlier version of this article: the last row of the table gave «≈30–60 kg Fe/ha/year (≈500–1,000 kg of product)». That figure was wrong by an order of magnitude and did not agree with the per-tree rates in the same table. The check: 4 g Fe per tree × 500 trees per hectare = 2 kg Fe/ha, that is about 33 kg of a 6% product. Even at high density and the top rate, 6 g × 800 trees = 4.8 kg Fe/ha, or 80 kg of product. «30–60 kg Fe/ha» would mean 60 to 120 g of elemental iron per tree — fifteen to thirty times what the same page recommends, at a matching cost and with no agronomic justification.

The rates are indicative, based on the literature for chelated Fe-EDDHA on fruit trees; the exact rate is set after leaf and soil analysis and after observing the symptoms. The grams of product are calculated for a formulation containing 6% Fe — if the product to hand has a different content, the quantity is adjusted accordingly.

Looking after the system: after every Fe application, run clean water through to flush the emitters completely. Where the water is hard, flush the lines preventively with acid (for example dilute nitric acid) at regular intervals, so that calcium carbonate deposits do not build up and block the emitters.
Scientific background / indicative bibliography
Lucena, J.J. (2003). Fe chelates for remediation of Fe chlorosis in strategy I plants. Journal of Plant Nutrition.  |  Álvarez-Fernández et al. (2005). Effects of Fe chelates on micronutrient uptake. Journal of Plant Nutrition.  |  Rombolà & Tagliavini (2006). Iron nutrition of fruit trees. In: Iron Nutrition in Plants and Rhizospheric Microorganisms, Springer.  |  On the ortho-ortho EDDHA fraction: García-Marco et al. (2006), European Journal of Agronomy. Rate ranges adapted from the technical guidance of Fe-EDDHA manufacturers for fruit trees in European practice.
Pastopoulos Agronomics  •  Technical information for growers  •  plantprotect.gr

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